Paste and powder paints should be mixed in quantities sufficient for immediate use only, as these materials often become unfit for application if allowed to stand for three or more hours.
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You can tell when the bucket of paint is getting low when the airless starts pumping really loud and doesn't stop. Simply tip the nearly empty bucket of paint, at an angle so that the mesh filter is covered and wait for the airless to catch up and stop pumping. Sometimes it's just easier to just to replace the bucket of paint with the new one and when that starts going down, pour the excess from the old bucket into the new one.
Practically every manufacturer has a "color system," a fat book of color chips with instructions for duplicating each chip. This is accomplished by intermixing cans of colored paint, by adding a concentrated color to a can of white or colored paint, or by adding concentrated color or colors to a can of neutral "base" paint. And for those who don't want any guesswork there's the Color Carousel that mixes the paints right in the store. Whatever the method, the result is a range of colors such as no amateur painter has seen.
Now that you have primed the airless, make sure that there isn't a tip in the gun of the airless and bring it over to the empty bucket. Since there is typically cleaning solution in the hose leading to the gun it is a good idea to spray that out until you see thick paint coming out. Once you have thick paint coming out you may put your tip back in. Remember that the tip will have an arrow on one side of the handle that shows which direction it must be in, in order to spray.
There are two bases of paint for your house: solvent-based (oil or alkyd) and water-based (latex). Oil-based paints dry slow - usually taking up to 24 hours. The best clean up for an oil-based paint is turpentine or paint thinner. Latex paints' advantage is that it dries relatively fast, but it is not desirable in hot weather or direct sunshine. The best clean up for latex paints requires just soap and water. So if you are painting the inside of your house, it is recommended to use water-based paints, while solvent-based paints are suggested for painting the exterior of your house.
To balance, you must grasp the interconnectedness of color schemes. All these interactions are defined in the color wheel, and it has been used to build color schemes for centuries.